Plastic shopping bags, an abundant source of litter on land and at sea, can be converted into diesel, natural gas and other useful petroleum products, researchers report.

The conversion produces significantly more energy than it requires and results in transportation fuels – diesel, for example – that can be blended with existing ultra-low-sulfur diesels and biodiesels. Other products, such as natural gas, naphtha (a solvent), gasoline, waxes and lubricating oils such as engine oil and hydraulic oil also can be obtained from shopping bags.

A report of the new study appears in the journal Fuel Processing Technology.

There are other advantages to the approach, which involves heating the bags in an oxygen-free chamber, a process called pyrolysis, said Brajendra Kumar Sharma, a senior research scientist at the Illinois Sustainable Technology Center who led the research. The ISTC is a division of the Prairie Research Institute at the University of Illinois.

Only about 13 percent of plastic bags used currently in the US are recycled. The rest of the bags end up in landfills or escape to the wild, blowing across the landscape and entering waterways.

Previous studies have used pyrolysis to convert plastic bags into crude oil. Sharma's team took the research further, however, by fractionating the crude oil into different petroleum products and testing the diesel fractions to see if they complied with national standards for ultra-low-sulfur diesel and biodiesel fuels.

"A mixture of two distillate fractions, providing an equivalent of U.S. diesel #2, met all of the specifications" required of other diesel fuels in use today – after addition of an antioxidant, Sharma said.

"This diesel mixture had an equivalent energy content, a higher cetane number (a measure of the combustion quality of diesel requiring compression ignition) and better lubricity than ultra-low-sulfur diesel," he said.

The researchers were able to blend up to 30 percent of their plastic-derived diesel into regular diesel, "and found no compatibility problems with biodiesel," Sharma said.

"It's perfect," he said. "We can just use it as a drop-in fuel in the ultra-low-sulfur diesel without the need for any changes."

(Report by Diana Yates for Illinois.edu)